Gol D. Roger was known as the "Pirate King," the strongest and most infamous being to have sailed the Grand Line. The capture and execution of Roger by the World Government brought a change throughout the world. His last words before his death revealed the existence of the greatest treasure in the world, One Piece. It was this revelation that brought about the Grand Age of Pirates, men who dreamed of finding One Piece—which promises an unlimited amount of riches and fame—and quite possibly the pinnacle of glory and the title of the Pirate King. Enter Monkey D. Luffy, a 17-year-old boy who defies your standard definition of a pirate. Rather than the popular persona of a wicked, hardened, toothless pirate ransacking villages for fun, Luffy's reason for being a pirate is one of pure wonder: the thought of an exciting adventure that leads him to intriguing people and ultimately, the promised treasure. Following in the footsteps of his childhood hero, Luffy and his crew travel across the Grand Line, experiencing crazy adventures, unveiling dark mysteries and battling strong enemies, all in order to reach the most coveted of all fortunes—One Piece.

In the Disabled Elderly Village, there live nine elderly people with unpredictable origins and the young man Qin Mu they raised. One day, the cows that Qin Mu was responsible for grazing began to speak human words. From then on, Qin Mu became more aware of the dangers and beauty of Daxu, a land abandoned by gods: demons descended with darkness, divine bones danced in the ruins, and dragon bones protected their young, a giant ship that drags the sun... No matter what kind of danger he faces, Qin Mu is fearless. He has integrated the skills passed down by the Nine Elders and vowed to carve out a world with his unparalleled hegemony.

Revealing himself to be a Dual Knight, Long Hao Chen triumphs in his match within his temple and advances to the finals. But before the grand finals can begin, ranking matches are conducted in each temple to determine the strongest within. During the rankings, Hao Chen is injured, enraging Sheng Cai'er and driving her to seek vengeance for what happened to him. Her actions cause a fight between the Knight Temple and Assassin Temple, only to be subdued after a shocking revelation—that Sheng Cai'er is a Reincarnated Saint. The finals for the Demon Hunting Team Competition begin with the division of the sixty remaining participants into six groups. The top sixteen participants are then further pitted against each other to determine the top three. Each of the top three will be rewarded with a spiritual stove and the right to pick their teammates. In order to become a knight that is capable of defeating the Demon Lord, Long Hao Chen must strive to be first in this competition so he can select the best teammates to give him a fighting chance.

Unaired episodes included in the Blu-ray box volumes.